Material Safety Data Sheet |
SECTION 1 PRODUCT AND COMPANY IDENTIFICATION
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Product Use: Fuel
SECTION 2 COMPOSITION/ INFORMATION ON INGREDIENTS
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| COMPONENTS | CAS NUMBER | AMOUNT |
| Aviation Gasoline | 100 %volume | |
| Naphtha, light alkylate | 64741-66-8 | 70 - 100 %volume |
| Naphtha, isomerization | 64741-70-4 | 0 - 10 %volume |
| Toluene | 108-88-3 | 0 - 20 %volume |
| Benzene | 71-43-2 | 0 - 1 %volume |
| Tetraethyl lead | 78-00-2 | < 4 ml/gal |
| Ethylene dibromide | 106-93-4 | < 4 ml/gal |
SECTION 3 HAZARDS IDENTIFICATION
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EMERGENCY OVERVIEW
- EXTREMELY FLAMMABLE LIQUID AND VAPOR. VAPOR MAY CAUSE FLASH FIRE
- HARMFUL OR FATAL IF SWALLOWED - MAY CAUSE LUNG DAMAGE IF SWALLOWED
- CAUSES EYE AND SKIN IRRITATION
- MAY CAUSE RESPIRATORY TRACT IRRITATION IF INHALED
- VAPOR HARMFUL
- SUSPECT CANCER HAZARD - MAY CAUSE CANCER
- BIRTH DEFECT HAZARD - CONTAINS MATERIAL THAT MAY CAUSE BIRTH DEFECTS
- MAY CAUSE DAMAGE TO:
- NERVOUS SYSTEM
- AUDITORY SYSTEM
DELAYED OR OTHER HEALTH EFFECTS:
Reproduction and Birth Defects: Contains material that may cause adverse reproductive effects if inhaled.
Cancer: Prolonged or repeated exposure to this material may cause cancer. Contains benzene, which has been classified as a carcinogen by the National Toxicology Program (NTP) and a Group 1 carcinogen (carcinogenic to humans) by the International Agency for Research on Cancer (IARC).
Contains ethylene dibromide which has been classified as a Group 2A carcinogen by the International Agency for Research on Cancer (IARC). Whole gasoline exhaust has been classified as a Group 2B carcinogen (possibly carcinogenic to humans) by the International Agency for Research on Cancer (IARC).
Contains benzene, which has been classified as an A1 Group Confirmed Human Carcinogen by the American Conference of Governmental Industrial Hygienists (ACGIH).
Target Organs: Repeated inhalation of this material at concentrations above the recommended exposure limit may cause damage to the following organ(s) based on animal data: Nervous System Auditory System
See Section 11 for additional information. Risk depends on duration and level of exposure.
SECTION 4 FIRST AID MEASURES
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SECTION 5 FIRE FIGHTING MEASURES
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SECTION 6 ACCIDENTAL RELEASE MEASURES
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SECTION 7 HANDLING AND STORAGE
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SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
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| Component | Country/ Agency |
TWA | STEL | Ceiling | Notation |
| Aviation Gasoline | CVX | 200 ppm | 1000 ppm | -- | -- |
| Benzene | ACGIH | .5 ppm (weight) | 2.5 ppm (weight) | -- | Skin A1 Skin |
| Benzene | CVX | 1 ppm (weight) | 5 ppm (weight) | -- | -- |
| Tetraethyl lead | ACGIH | .1 mg/m3 | -- | -- | Skin as Pb |
| Toluene | ACGIH | 50 ppm (weight) | -- | -- | Skin A4 |
NOTE ON OCCUPATIONAL EXPOSURE LIMITS: Consult local authorities for acceptable provincial values in Canada. Consult the Canadian Standards Association Standard 94.4-2002 Selection, Use and Care of Respirators.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
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SECTION 10 STABILITY AND REACTIVITY
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SECTION 11 TOXICOLOGICAL INFORMATION
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IMMEDIATE HEALTH EFFECTS
This product contains benzene.
This product contains toluene.
This material contains organic lead. Organic lead (as Pb) is toxic by ingestion, inhalation, and skin contact. Signs and symptoms of chronic or subacute poisoning may initially include insomnia and restlessness; progressing into nausea, vomiting, loss of appetite, dizziness, abnormal blood pressure and temperature, increased respiratory rate, and skin pallor. In addition, continued exposure or acute poisoning may result in weakness, loss of weight, visual and auditory hallucinations, violent or maniacal type attacks, increased excitability, coarse tremors, convulsions and death.
Eye Irritation: The eye irritation hazard is based on evaluation of data for similar materials or product components.
Skin Irritation: The skin irritation hazard is based on evaluation of data for similar materials or product components.
Skin Sensitization: The skin sensitization hazard is based on evaluation of data for similar materials or product components.
Acute Dermal Toxicity: LD50: >3.75g/kg (rabbit). The acute dermal toxicity hazard is based on evaluation of data for similar materials or product components.
Acute Oral Toxicity: LD50: >5 ml/kg (rat) The acute oral toxicity hazard is based on evaluation of data for similar materials or product components.
Acute Inhalation Toxicity: The acute inhalation toxicity hazard is based on evaluation of data for similar materials or product components.For additional information on the acute toxicity of the components, call the technical information center.
ADDITIONAL TOXICOLOGY INFORMATION:
This product contains light alkylate naphtha. An inhalation study in rats found no adverse effects on male or female reproductive abilities and no birth defects in pups born to the exposed mothers. This study was done with that portion of light alkylate naphtha that distilled below 145 F (C4 to C6 hydrocarbons). The concentrations used in the study were up to 25,000 mg/m3 which is 60% of the lower explosive limit. That dose was also the no-observed-adverse-effect level.
GENETIC TOXICITY/CANCER: Repeated or prolonged breathing of benzene vapor has been associated with the development of chromosomal damage in experimental animals and various blood diseases in humans ranging from aplastic anemia to leukemia (a form of cancer). All of these diseases can be fatal. In some individuals, benzene exposure can sensitize cardiac tissue to epinephrine which may precipitate fatal ventricular fibrillation.
REPRODUCTIVE/DEVELOPMENTAL TOXICITY: No birth defects have been shown to occur in pregnant laboratory animals exposed to doses not toxic to the mother. However, some evidence of fetal toxicity such as delayed physical development has been seen at such levels. The available information on the effects of benzene on human pregnancies is inadequate but it has been established that benzene can cross the human placenta.
OCCUPATIONAL: The OSHA Benzene Standard (29 CFR 1910.1028) contains detailed requirements for training, exposure monitoring, respiratory protection and medical surveillance triggered by the exposure level. Refer to the OSHA Standard before using this product.
GENERAL TOXICITY: The primary effects of exposure to toluene in animals and humans are on the central nervous system. Solvent abusers, who typically inhale high concentrations (thousands of ppm) for brief periods of time, in addition to experiencing respiratory tract irritation, often suffer permanent central nervous system effects that include tremors, staggered gait, impaired speech, hearing and vision loss, and changes in brain tissue. Death in some solvent abusers has been attributed to cardiac arrhythmias, which appear to be have been triggered by epinephrine acting on solvent sensitized cardiac tissue. Although liver and kidney effects have been seen in some solvent abusers, results of animal testing with toluene do not support these as primary target organs.
HEARING: Humans who were occupationally exposed to concentrations of toluene as low as 100 ppm for long periods of time have experienced hearing deficits. Hearing loss, as demonstrated using behavioral and electrophysiological testing as well as by observation of structural damage to cochlear hair cells, occurred in experimental animals exposed to toluene. It also appears that toluene exposure and noise may interact to produce hearing deficits.
COLOR VISION: In a single study of workers exposed to toluene at levels under 50 ppm, small decreases in the ability to discriminate colors in the blue-yellow range have been reported for female workers. This effect, which should be investigated further, is very subtle and would not likely have been noticed by the people tested.
REPRODUCTIVE/DEVELOPMENTAL TOXICITY: Toluene may also cause mental and/or growth retardation in the children of female solvent abusers who directly inhale toluene (usually at thousands of ppm) when they are pregnant. Toluene caused growth retardation in rats and rabbits when administered at doses that were toxic to the mothers. In rats, concentrations of up to 5000 ppm did not cause birth defects. No effects were observed in the offspring at doses that did not intoxicate the pregnant animals. The exposure level at which no effects were seen (No Observed Effect Level, NOEL) is 750 ppm in the rat and 500 ppm in the rabbit.
SECTION 12 ECOLOGICAL INFORMATION
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ENVIRONMENTAL FATE
This material is expected to be readily biodegradable. Following spillage, the more volatile components of gasoline will be rapidly lost, with concurrent dissolution of these and other constituents into the water. Factors such as local environmental conditions (temperature, wind, mixing or wave action, soil type, etc), photo-oxidation, biodegradation and adsorption onto suspended sediments, can contribute to the weathering of spilled gasoline.
SECTION 13 DISPOSAL CONSIDERATIONS
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SECTION 14 TRANSPORT INFORMATION
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TC Shipping Description: UN1203, GASOLINE, 3, II, MARINE POLLUTANT(GASOLINE LEADED)
IMO/IMDG Shipping Description: UN1203, GASOLINE, 3, II, MARINE POLLUTANT(GASOLINE LEADED), FLASH POINT SEE SECTION 5
ICAO/IATA Shipping Description: UN1203, GASOLINE, 3, II
DOT Shipping Description: GASOLINE, 3, UN1203, II, MARINE POLLUTANT (LEADED GASOLINE), RQ (LEAD)
SECTION 15 REGULATORY INFORMATION
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| 01-1=IARC Group 1 |
| 01-2A=IARC Group 2A |
| 01-2B=IARC Group 2B |
| 35=WHMIS IDL |
| Benzene | 01-1, 35 |
| Ethylene dibromide | 01-2A, 35 |
| Tetraethyl lead | 35 |
| Toluene | 35 |
CHEMICAL INVENTORIES:
All components comply with the following chemical inventory requirements: AICS (Australia), EINECS (European Union), IECSC (China), KECI (Korea), TSCA (United States).
WHMIS CLASSIFICATION:
Class B, Division 2: Flammable Liquids
Class D, Division 2, Subdivision A: Very Toxic Material -
Chronic Toxic Effects
Teratogenicity and Embryotoxicity
Carcinogenicity
Class D, Division 2, Subdivision B: Toxic Material -
Skin or Eye Irritation
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations. (See Hazardous Products Act (HPA), R.S.C. 1985, c.H-3,s.2).
MSDS PREPARATION:
This Material Safety Data Sheet has been prepared by the Toxicology and Health Risk Assessment Unit, ERTC, P.O. Box 1627, Richmond, CA 94804, (888)676-6183.
SECTION 16 OTHER INFORMATION
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TLV - Threshold Limit Value
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TWA - Time Weighted Average
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STEL - Short-term Exposure Limit
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PEL - Permissible Exposure Limit
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CAS - Chemical Abstract Service Number
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ACGIH - American Conference of Government Industrial Hygienists
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IMO/IMDG - International Maritime Dangerous Goods Code |
| API - American Petroleum Institute | MSDS - Material Safety Data Sheet |
| CVX - Chevron | NFPA - National Fire Protection Association (USA) |
| DOT - Department of Transportation (USA) | NTP - National Toxicology Program (USA) |
| IARC - International Agency for Research on Cancer | OSHA - Occupational Safety and Health Administration |
| The above information is based on the data of which we are aware and is believed to be correct as of the date hereof. Since this information may be applied under conditions beyond our control and with which we may be unfamiliar and since data made available subsequent to the date hereof may suggest modifications of the information, we do not assume any responsibility for the results of its use. This information is furnished upon condition that the person receiving it shall make his own determination of the suitability of the material for his particular purpose. |